Abundance of the chemical elements 392828 224577495 2008-07-09T14:25:01Z Iridescent 937705 Reverted edits by [[Special:Contributions/92.5.5.30|92.5.5.30]] to last version by Arkuat (using [[WP:HG|Huggle]]) {{seealso|Abundances of the elements (data page)}} The '''abundance''' of a [[chemical element]] measures how relatively common the element is, or how much of the element there is by comparison to all other elements. Abundance may be variously measured by the mass-fraction (the same as weight fraction), or mole-fraction (fraction of atoms, or sometimes fraction of molecules, in gases), or by volume fraction. Measurement by volume-fraction is a common abundance measure in mixed gases such as atmospheres, which is close to molecular mole-fraction for ideal gas mixtures (i.e., gas mixtures at relatively low densities and pressures). For example, the mass-fraction abundance of oxygen in water is about 89%, because that is the fraction of water's mass which is oxygen. However, the mole-fraction abundance of oxygen in water is only 33% because only 1 atom in 3 in water is an oxygen atom. In the universe as a whole, and in the atmospheres of gas-giant planets such as Jupiter, the mass-fraction abundances of hydrogen and helium are about 74% and 23-25% respectively, while the (atomic) mole-fractions of these elements are closer to 92% and 8%. However, since hydrogen is diatomic while helium is not in the conditions of Jupiter's outer atmosphere, the ''molecular'' mole-fraction (fraction of total gas molecules, or fraction of atmosphere by volume) of hydrogen in the outer atmosphere of Jupiter is about 86%, and for helium, 13%. Most abundances in this article are given as mass-fraction abundances. == Abundance of elements in the Universe == ''See also: [[Stellar population]], [[Cosmochemistry]], [[Astrochemistry]]'' The elements - namely ordinary ([[baryon]]ic) matter made out of [[proton]]s and [[neutron]]s (as well as [[electron]]s) - are only a small part of the content of the Universe. [[Observational cosmology|Cosmological observations]] suggest that about 73% of the universe consists of [[dark energy]], 23% is composed of [[dark matter]] and only 4% corresponds to the visible [[baryon]]ic [[matter]] which constitutes [[stars]], [[planets]] and [[living]] beings. Dark matter has not yet been detected in a [[particle physics]] detector, and the nature of the dark energy is not yet understood. Most standard (baryonic) matter is found in the form of atoms or [[plasma (physics)|plasma]], although there are many other unusual kinds of matter. Other forms of baryonic matter include [[white dwarf]]s, [[neutron star]]s and [[black hole]]s. Standard matter also exists as [[photons]] (mostly in the [[cosmic microwave background]]) and [[neutron]]s. [[Hydrogen]] is the most abundant element in the known [[Universe]]; [[helium]] is second. However, after this, the rank of abundance does not continue to correspond to the [[atomic number]]; [[oxygen]] has abundance rank 3, but atomic number 8. All others are substantially less common. The abundance of the lightest elements is well predicted by the [[Lambda-CDM model|standard cosmological model]], since they were mostly produced shortly (i.e., within a few hundred seconds) after the [[Big Bang]], in a process known as [[Big Bang nucleosynthesis]]. Heavier elements were mostly produced much later, inside [[star]]s. Helium-3 is rare on Earth and sought-after for use in nuclear fusion research. More abundant helium-3 is thought to exist on the Moon. Additional helium is produced by the [[nuclear fusion|fusion]] of hydrogen inside stellar cores by a variety of processes including the [[proton-proton chain]] and the [[CNO cycle]]. Hydrogen and helium are estimated to make up roughly 74% and 24% of all baryonic matter in the universe respectively. Despite comprising only a very small fraction of the universe, the remaining "heavy elements" can greatly influence astronomical phenomena. Only about 2% (by mass) of the [[Milky Way galaxy]]'s disk is composed of heavy elements. These other elements are generated by stellar processes<ref>H. E. Suess and H. C. Urey (1956) Abundances of the elements, ''Rev Mod Phys'' '''28''':53-74.</ref><ref>A. G. W. Cameron (1973) Abundances of the elements in the solar system, ''Space Sci Rev'' '''15''':121-146.</ref><ref>E. Anders and M. Ebihara (1982) Solar-system abundances of the elements, ''Geochim. Cosmochim. Acta'' '''46''':2363-2380.</ref>. In [[astronomy]], a "metal" is any element other than hydrogen or helium. This distinction is significant because hydrogen and helium (together with trace amounts of [[lithium]]) are the only elements that occur naturally without the nuclear fusion activity of [[star]]s. Thus, the [[metallicity]] of a [[galaxy]] or other object is an indication of past stellar activity. These are the ten most common elements in the Universe as measured in parts per million, by mass {{Fact|date=February 2007}}: {|class="wikitable" |- !Element!!Parts per million |- |[[Hydrogen]] |739,000 |- |[[Helium]] |240,000 |- |[[Oxygen]] |10,700 |- |[[Carbon]] |4,600 |- |[[Neon]] |1,340 |- |[[Iron]] |1,090 |- |[[Nitrogen]] |950 |- |[[Silicon]] |650 |- |[[Magnesium]] |580 |- |[[Sulfur]] |440 |- |All Others |650 |} == Abundance of elements on Earth == {{seealso|Earth#Chemical composition}} The [[Earth]] formed from the same cloud of matter that formed the Sun, but the planets acquired different compositions during the [[formation and evolution of the solar system]]. The [[history of Earth]] caused parts of this planet to have differing concentrations of the elements. === Abundance of elements in Earth's crust === This graph illustrates the relative abundance of the chemical elements in Earth's upper continental crust. [[Image:Relative abundance of elements.png|thumb|300px|right|Abundance (atom fraction) of the chemical elements in Earth's upper continental crust as a function of atomic number.]] Many of the elements shown in the graphic are classified into (partially overlapping) categories: #rock-forming elements (major elements in green field and minor elements in light green field); #[[rare earth element]]s (lanthanides, La-Lu, and Y; labeled in blue); #major industrial metals (global production >~3×10<sup>7</sup> kg/year; labeled in bold); #[[precious metal]]s (italic); #the nine rarest "metals" &mdash; the six [[platinum group]] elements plus [[Gold|Au]], [[Rhenium|Re]], and [[Tellurium|Te]] (a metalloid). Note that there are two breaks where the unstable elements [[technetium]] (atomic number: 43) and [[promethium]] (atomic number: 61) would be. These are very rare, as on Earth they are only produced through the [[Nuclear fission|fission]] of heavy radioactive elements (for example, [[uranium]] or [[thorium]]). Both elements have been identified spectroscopically in the atmospheres of stars, where they are produced by ongoing nucleosynthetic processes. There are also breaks where the six [[noble gas]]es would be as they are found in the Earth's crust due to decay chains from radioactive elements and are therefore not included. The six very rare, highly radioactive elements ([[polonium]], [[astatine]], [[francium]], [[radium]], [[actinium]] and [[protactinium]]) are not included, as their natural abundances are too low to have been accurately measured. [[Oxygen]] and [[silicon]] are notably common; they form several common [[silicate mineral]]s. ===="Rare earth" element abundances==== "Rare" earth elements is a historical misnomer; persistence of the term reflects unfamiliarity rather than true rarity. The more abundant [[rare earth element]]s are each similar in crustal concentration to commonplace industrial metals such as chromium, nickel, copper, zinc, molybdenum, tin, tungsten, or lead. Even the two least abundant rare earth elements ([[Thulium|Tm]], [[Lutetium|Lu]]) are nearly 200 times more common than gold. However, in contrast to ordinary base and precious metals, rare earth elements have very little tendency to become concentrated in exploitable ore deposits. Consequently, most of the world's supply of rare earth elements comes from only a handful of sources. Differences in abundances of individual rare earth elements in the upper continental crust of Earth represent the superposition of two effects, one nuclear and one geochemical. First, rare earth elements with even atomic numbers (<sub>58</sub>Ce, <sub>60</sub>Nd, ...) have greater cosmic and terrestrial abundances than adjacent rare earth elements with odd atomic numbers (<sub>57</sub>La, <sub>59</sub>Pr, ...). Second, the lighter rare earth elements are more incompatible (because they have larger ionic radii) and therefore more strongly concentrated in the continental crust than the heavier rare earth elements. In most rare earth deposits, the first four rare earth elements - [[Lanthanum|La]], [[Cerium|Ce]], [[Praseodymium|Pr]], and [[Neodymium|Nd]] - constitute 80 to 99% of the total. === Ocean === {| class="wikitable" style="float: right; margin: 0 0 1em 1em;" |+ Elemental composition of Earth's ocean water (by mass) |- !Element !Percent !Element !Percent |- |[[Oxygen]] |85.84 |[[Sulfur]] |0.091 |- |[[Hydrogen]] |10.82 |[[Calcium]] |0.04 |- |[[Chlorine]] |1.94 |[[Potassium]] |0.04 |- |[[Sodium]] |1.08 |[[Bromine]] |0.0067 |- |[[Magnesium]] |0.1292 |[[Carbon]] |0.0028 |} See [[sea water]] for abundance of elements in the ocean, but note that that list is by mass - a list by [[molarity]] (mole-fraction) would look very different for the first 4 elements; specifically, hydrogen would comprise nearly two-thirds of the number of all atoms because hydrogen itself comprises two of the three atoms of all water molecules. === Atmosphere === The order of elements by volume-fraction (which is approximately molecular mole-fraction) in the [[Earth's atmosphere|atmosphere]] is [[nitrogen]] (78.1%), [[oxygen]] (20.9%), [[argon]] (0.96%), followed by (in uncertain order) carbon and hydrogen because water vapor and carbon dioxide, which represent most of these two elements in the air, are variable components. Sulfur, phosphorus, and all other elements are present in significantly lower proportions. According to the above graphic, argon, a significant if not major component of the atmosphere, does not appear in the crust at all. This is because the atmosphere has a far smaller mass than the crust, so argon remaining in the crust contributes little to mass-fraction there, while at the same time buildup of argon in the atmosphere has become large enough to be significant. <!--it's not that argon can't stay in the crust due to being inert. Helium stays in the crust well enough! And there is argon trapped in rocks or K-Ar dating would not work. Instead, the reason is the one given.--> === Human body === By mass, human cells consist of 65-90% water (H<sub>2</sub>O), and a significant portion is composed of carbon-containing organic molecules. Oxygen therefore contributes a majority of a human body's mass, followed by carbon. 99% of the mass of the human body is made up of the six elements: oxygen, carbon, hydrogen, nitrogen, calcium, and phosphorus. {|class="wikitable" |- !Element !Percent by mass |- |[[Oxygen]] |65 |- |[[Carbon]] |18 |- |[[Hydrogen]] |10 |- |[[Nitrogen]] |3 |- |[[Calcium]] |1.5 |- |[[Phosphorus]] |1.2 |- |[[Potassium]] |0.2 |- |[[Sulfur]] |0.2 |- |[[Chlorine]] |0.2 |- |[[Sodium]] |0.1 |- |[[Magnesium]] |0.05 |- |[[Iron]], [[Cobalt]], [[Copper]], [[Zinc]], [[Iodine]] |<0.05 each |- |[[Selenium]], [[Fluorine]] |<0.01 each |- |} {{cite book | last = Chang | first = Raymond | title = Chemistry, Ninth Edition | publisher = McGraw-Hill | date = 2007 | pages = p. 52 | isbn = 0-07-110595-6 }} == See also == *[[Abundances of the elements (data page)]] *[[Chemical composition of living beings]] *[[Chemical Galaxy]] (a new periodic table) *[[Chemical makeup of the human body]] *[[Cosmochemical Periodic Table of the Elements in the Solar System]] *[[Natural abundance]] (isotopic abundance) *[[Periodic table]] == Footnotes and references == {{refs}} == External links == * [http://www.science.co.il/PTelements.asp?s=Earth List of elements in order of abundance in the Earth's crust] (only correct for the twenty most common elements) * [http://web.archive.org/web/20060901133923/http://www.astro.wesleyan.edu/~bill/courses/astr231/wes_only/element_abundances.pdf Cosmic abundance of the elements and nucleosynthesis] ---- :''Parts of this article are taken from the public domain sources at http://geopubs.wr.usgs.gov/fact-sheet/fs087-02/ and http://imagine.gsfc.nasa.gov/docs/dict_ei.html Please update as needed. '' {{PeriodicTablesFooter}} [[Category:Chemical elements| ]] [[Category:Astrochemistry]] [[de:Elementhäufigkeit]] [[it:Abbondanza chimica]] [[pl:Częstość występowania pierwiastków we Wszechświecie]] [[pt:Abundância dos elementos químicos]] [[ru:Распространённость химических элементов]]