History of thermodynamics
2281782
226025231
2008-07-16T14:21:18Z
Jagged 85
468111
/* Short history */
[[Image:Savery-engine.jpg|225px|right|thumb|The 1698 '''Savery Engine''' - the world's first [[engine]] built by [[Thomas Savery]] as based on the designs of [[Denis Papin]].]]
The '''history of thermodynamics''' is a fundamental strand in the [[history of physics]], the [[history of chemistry]], and the [[history of science]] in general. Owing to the relevance of [[thermodynamics]] in much of [[science]] and [[technology]], its history is finely woven with the developments of [[classical mechanics]], [[quantum mechanics]], [[magnetism]], and [[chemical kinetics]], to more distant applied fields such as [[meteorology]], [[information theory]], and [[biology]] ([[physiology]]), and to [[technology|technological]] developments such as the [[steam engine]], [[internal combustion engine]], [[cryogenics]] and [[electricity generation]]. The development of thermodynamics both drove and was driven by [[atomic theory]]. It also, albeit in a subtle manner, motivated new directions in [[probability]] and [[statistics]]; see, for example, the [[timeline of thermodynamics, statistical mechanics, and random processes]].
==Short history==<!-- This section is linked from [[Vacuum pump]] -->
{{main|Timeline of thermodynamics, statistical mechanics, and random processes}}
The '''short history of thermodynamics''', with focus on the essential stepping stones that inherently functioned to stimulate modern thermodynamics, began with the arguments of the 5th century Greek philosopher [[Parmenides]]. In his only known work, a poem conventionally titled 'On Nature', Parmenides uses verbal reasoning to postulate that a [[void]], essentially what is now known as a [[vacuum]], in nature could not occur. This view was supported by [[Aristotle]], [[Al-Farabi]] (Alpharabius) and others,<ref name=Stanford>[http://plato.stanford.edu/entries/arabic-islamic-natural Arabic and Islamic Natural Philosophy and Natural Science], ''[[Stanford Encyclopedia of Philosophy]]''</ref> but was criticized by [[Leucippus]], [[Hero of Alexandria]], [[Ibn al-Haytham]] (Alhazen) and others.<ref>{{Citation |last=El-Bizri |first=Nader |year=2007 |title=In Defence of the Sovereignty of Philosophy: Al-Baghdadi's Critique of Ibn al-Haytham's Geometrisation of Place |journal=Arabic Sciences and Philosophy |volume=17 |pages=57–80 |publisher=[[Cambridge University Press]] |doi=10.1017/S0957423907000367 }}</ref> The first [[suction]] [[pump]], a device which sucks fluids into a partial vacuum, was described in 1206 by [[Al-Jazari]], and this suction pump later appeared in Europe from the 15th century.<ref name=Hill2>[[Donald Routledge Hill]], "Mechanical Engineering in the Medieval Near East", ''Scientific American'', May 1991, pp. 64-69 ([[cf.]] [[Donald Routledge Hill]], [http://home.swipnet.se/islam/articles/HistoryofSciences.htm Mechanical Engineering])</ref><ref name=Hassan/> Parmenides' statement was eventually disproved conclusively in the 17th century, when [[Otto von Guericke]] built a [[vacuum pump]], which was used to affix together his famous “[[Magdeburg Hemispheres]]” that he so proudly displayed around Europe in the mid 17th century. Soon thereafter, stimulated into conception by von Guericke’s vacuum pump design, the [[steam engine]] was built. The rest is thermodynamic history.
[[Image:Hg_Barometer.svg|thumb|75px|right|Schematic of [[Evangelista Torricelli]]'s 1643 mercury column experiment]]
==Long history==
The '''long history of thermodynamics''', may very well rightly include contributions from nearly all branches of science:
===Contributions from ancient and medieval times===
{{See also|History of heat|Vacuum}}
In the [[western philosophy|Western philosophical]] tradition, after much debate about the primal element among earlier [[pre-Socratic philosophy|pre-Socratic philosopher]]s, [[Empedocles]] proposed a four-element theory, in which all substances derive from [[earth (classical element)|earth]], [[water (classical element)|water]], [[air (classical element)|air]], and [[fire (classical element)|fire]]. The Empedoclean element of fire is perhaps the principal ancestor of later concepts such as [[phlogiston]] and [[caloric theory|caloric]].
[[Atomism]] is a central part of today's relationship between thermodynamics and statistical mechanics. Ancient thinkers such as [[Leucippus]] and [[Democritus]], and later the [[Epicureans]], by advancing atomism, laid the foundations for the later [[atomic theory]]. Until experimental proof of [[atoms]] was later provided in the [[20th century]], the atomic theory was driven largely by philosophical considerations and scientific intuition. Consequently, ancient philosophers used atomic theory to reach conclusions that today may be viewed as immature: for example, Democritus gives a vague atomistic description of the soul, namely that it is "built from thin, smooth, and round atoms, similar to those of fire".
The 5th century Greek philosopher [[Parmenides]], in his only known work, a poem conventionally titled ''On Nature'', uses verbal reasoning to postulate that a [[void]], essentially what is now known as a [[vacuum]], in nature could not occur. This view was supported by the arguments of [[Aristotle]], but was criticized by [[Leucippus]] and [[Hero of Alexandria]].
In the 10th century, the [[Islamic physics|Muslim physicist]], [[Al-Farabi]] (Alpharabius), carried out [[experiment]]s concerning the existence of a [[vacuum]], in which he investigated handheld plungers in water. He concluded that the air's volume can expand to fill the available space, and he suggested that the concept of a perfect vacuum was incoherent.<ref name=Stanford>[http://plato.stanford.edu/entries/arabic-islamic-natural Arabic and Islamic Natural Philosophy and Natural Science], ''[[Stanford Encyclopedia of Philosophy]]''</ref> In the early 11th century, the Muslim physicist [[Ibn al-Haytham]] (Alhazen, 965-1039) and the [[Mu'tazili]] [[Kalam|theologians]] disagreed with Aristotle and Al-Farabi, and they supported the existence of a void. Using [[geometry]], Ibn al-Haytham [[Islamic mathematics|mathematially]] demonstrated that place (''al-makan'') is the imagined three-dimensional void between the inner surfaces of a containing body.<ref>{{Citation |last=El-Bizri |first=Nader |year=2007 |title=In Defence of the Sovereignty of Philosophy: Al-Baghdadi's Critique of Ibn al-Haytham's Geometrisation of Place |journal=Arabic Sciences and Philosophy |volume=17 |pages=57–80 |publisher=[[Cambridge University Press]] |doi=10.1017/S0957423907000367 }}</ref>
Also in the early 11th century, the [[Persian people|Persian]] physicist [[Avicenna]] (Ibn Sina) was the first to measure relative "[[coldness]]" or "[[hotness]]" of air (now known as [[temperature]]), using an air [[thermometer]],<ref name=Briffault>[[Robert Briffault]] (1938). ''The Making of Humanity'', p. 191</ref><ref name=Hayani>Fatima Agha Al-Hayani (2005). "Islam and Science: Contradiction or Concordance", ''Zygon'' '''40''' (3), p. 565-576.</ref> which was similar to an earlier device used by [[Philo of Byzantium]] for another purpose. The hypothesis that [[heat]] is a form of [[Motion (physics)|motion]] was initially proposed in the 13th century, by the medieval [[Islamic physics|Arabic physicist]] ʻAbd Allah Baydawi.<ref>{{citation|title=Nature, man and God in medieval Islam: ʻAbd Allah Baydawi's text, Tawaliʻ al-anwar min matali' al-anzar|first1=ʻAbd Allāh ibn ʻUmar|last1=Bayḍāwī|first2=Maḥmūd ibn ʻAbd al-Raḥmān|last2=Iṣfahānī|first3=Edwin Elliott|last3=Calverley|first4=James Wilson|last4=Pollock|year=2002|pubclisher=[[Brill Publishers]]|isbn=9004121021|pages=409 & 492}}</ref> The first [[suction]] [[pump]], a device which sucks fluids into a partial vacuum, was invented in 1206 by the [[Timeline of Muslim scientists and engineers|Arabian engineer]] and [[Inventions in the Islamic world|inventor]], [[Al-Jazari]]. The suction pump later appeared in Europe from the 15th century.<ref name=Hill2>[[Donald Routledge Hill]], "Mechanical Engineering in the Medieval Near East", ''Scientific American'', May 1991, pp. 64-69 ([[cf.]] [[Donald Routledge Hill]], [http://home.swipnet.se/islam/articles/HistoryofSciences.htm Mechanical Engineering])</ref><ref name=Hassan>{{cite web|author=[[Ahmad Y Hassan]]|title=The Origin of the Suction Pump: Al-Jazari 1206 A.D.|url=http://www.history-science-technology.com/Notes/Notes%202.htm|accessdate=2008-07-16}}</ref>
In 1643, [[Galileo Galilei]], while generally accepting the ''horror vacui'' of Aristotle, believed that nature’s vacuum-abhorrence is limited. Pumps operating in mines had already proven that nature would only fill a vacuum with water up to a height of 30 feet. Knowing this curious fact, Galileo encouraged his former pupil [[Evangelista Torricelli]] to investigate these supposed limitations. Torricelli did not believe that vacuum-abhorrence was responsible for raising the water. Rather, he reasoned, it was the result of the pressure exerted on the liquid by the surrounding air. To prove this theory, he filled a glass tube, sealed at one end, filled with mercury and upended it into a dish also containing mercury. Only a portion of the tube emptied (as shown adjacent); 30 inches of the liquid remained. As the mercury emptied, a [[vacuum]] was created at the top of the tube. This, the first man-made vacuum, effectively disproved Aristotle’s theory and affirmed the existence of vacuums in nature.
=== Transition from chemistry to thermochemistry ===
{{see also|History of chemistry}}
The theory of phlogiston arose in the 17th century, late in the period of alchemy. Its replacement by caloric theory in the 18th century is one of the historical markers of the transition from alchemy to chemistry. Phlogiston was supposed to be liberated from combustible substances during [[combustion|burning]], and from [[metal]]s during the process of [[rusting]].
The first substantial experimental challenges to caloric theory arose in [[Benjamin Thompson|Rumford]]'s [[1798]] work, though his experiments were poorly controlled, and most of the scientific establishment had enough confidence in caloric theory to believe that it could account for the results. More quantitative studies by [[James Prescott Joule]] in [[1843]] onwards provided soundly reproducible phenomena, but still met with scant enthusiasm. [[William Thomson]], for example, was still trying to explain Joule's observations within a caloric framework as late as [[1850]]. The utility and explanatory power of [[kinetic theory]], however, soon started to displace caloric and it was largely obsolete by the end of the [[19th century]].
=== Phenomenological thermodynamics ===
*[[Boyle's law]] ([[1662]])
*[[Charles's law]] was first published by [[Joseph Louis Gay-Lussac]] in [[1802]], but he referenced unpublished work by [[Jacques Charles]] from around [[1787]]. The relationship had been anticipated by the work of [[Guillaume Amontons]] in [[1702]].
*[[Gay-Lussac's law]] ([[1802]])
===Modern theory===
At its origins, thermodynamics was the study of [[engines]]. A precursor of the engine was designed by the German scientist [[Otto von Guericke]] who in 1650 built and designed the world's first [[vacuum pump]] and created the world's first ever [[vacuum]] known as the [[Magdeburg hemispheres]]. He was driven to make a vacuum in order to disprove [[Aristotle]]'s long-held supposition that 'Nature abhors a vacuum'.
Shortly thereafter, Irish physicist and chemist [[Robert Boyle]] had learned of Guericke's designs and in 1656, in coordination with English scientist [[Robert Hooke]], built an air pump. Using this pump, Boyle and Hooke noticed the pressure-temperature-volume correlation. In time, the [[ideal gas law]] was formulated. Then, in 1679, based on these concepts, an associate of Boyle's named [[Denis Papin]] built a bone digester, which is a closed vessel with a tightly fitting lid that confines steam until a high pressure is generated.
Later designs implemented a steam release valve to keep the machine from exploding. By watching the valve rhythmically move up and down, Papin conceived of the idea of a piston and cylinder engine. He did not however follow through with his design. Nevertheless, in 1697, based on Papin’s designs, engineer [[Thomas Savery]] built the first engine. Although these early engines were crude and inefficient, they attracted the attention of the leading scientists of the time. One such scientist was [[Nicolas Léonard Sadi Carnot|Sadi Carnot]], the “father of thermodynamics”, who in 1824 published ''“Reflections on the Motive Power of Fire”,'' a discourse on heat, power, and engine efficiency. This marks the start of thermodynamics as a modern science.
[[Image:Maquina vapor Watt ETSIIM.jpg|right|thumb|300px|A [[Watt steam engine]], the [[steam engine]] that propelled the Industrial Revolution in Britain and the world]]
Hence, prior to [[1698]] and the invention of the [[steam engine|Savery Engine]], horses were used to power pulleys, attached to buckets, which lifted water out of flooded salt mines in England. In the years to follow, more variations of steam engines were built, such as the [[newcomen steam engine|Newcomen Engine]], and later the [[watt steam engine|Watt Engine]]. In time, these early engines would eventually be utilized in place of horses. Thus, each engine began to be associated with a certain amount of "horse power" depending upon how many horses it had replaced. The main problem with these first engines was that they were slow and clumsy, converting less than 2% of the input [[fuel]] into useful work. In other words, large quantities of coal (or wood) had to be burned to yield only a small fraction of work output. Hence the need for a new science of engine [[dynamics (mechanics)|dynamics]] was born.
[[Image:Carnot2.jpg|150px|left|thumb|Sadi Carnot (1796-1832): the "father" of thermodynamics]]
Most cite [[Nicolas Léonard Sadi Carnot|Sadi Carnot’s]] [http://www.thermohistory.com/carnot.pdf 1824 paper] ''Reflections on the Motive Power of Fire'' as the starting point for thermodynamics as a modern science. Carnot defined "motive power" to be the expression of the ''useful effect'' that a motor is capable of producing. Herein, Carnot introduced us to the first modern day definition of "[[Mechanical work|work]]": ''weight lifted through a height''. The desire to understand, via formulation, this ''useful effect'' in relation to "work" is at the core of all modern day thermodynamics.
The name "thermodynamics," however, did not arrive until some twenty-five years later when, in 1849, the British mathematician and physicist [[William Thomson]] (Lord Kelvin) coined the term ''thermodynamics'' in a paper on the efficiency of steam engines. In 1850, the famed mathematical physicist [[Rudolf Clausius]] originated and defined the term enthalpy '''''H''''' to be the total heat content of the system, stemming from the Greek word ''enthalpein'' meaning ''to warm'', and defined the term entropy '''''S''''' to be the heat lost or turned into waste, stemming from the Greek word ''entrepein'' meaning ''to turn''.
<!-- Commented out because image was deleted: [[Image:Baron Kelvin.jpg|thumb|right|Lord Kelvin {{deletable image-caption}}]] -->
In association with Clausius, in 1871, a Scottish mathematician and physicist [[James Clerk Maxwell]] formulated a new branch of thermodynamics called ''Statistical Thermodynamics'', which functions to analyze large numbers of particles at [[thermodynamic equilibrium|equilibrium]], i.e., systems where no changes are occurring, such that only their average properties as temperature '''''T''''', pressure '''''P''''', and volume '''''V''''' become important.
Soon thereafter, in 1875, the Austrian physicist [[Ludwig Boltzmann]] formulated a precise connection between entropy '''''S''''' and molecular motion:
:<math>S=k\log W \,</math>
being defined in terms of the number of possible states [W] such motion could occupy, where k is the [[Boltzmann's constant]]. The following year, 1876, was a seminal point in the development of human thought. During this essential period, chemical engineer [[Willard Gibbs]], the first person in America to be awarded a PhD in engineering (Yale), published an obscure 300-page paper titled: ''On the Equilibrium of Heterogeneous Substances'', wherein he formulated one grand equality, the [[Gibbs free energy]] equation, which gives a measure the amount of "useful work" attainable in reacting systems.
Building on these foundations, those as [[Lars Onsager]], [[Erwin Schrödinger]], and [[Ilya Prigogine]], and others, functioned to bring these engine "concepts" into the thoroughfare of almost every modern-day branch of science.
=== Kinetic theory ===
The idea that [[heat]] is a form of [[Motion (physics)|motion]] is perhaps an ancient one and is certainly discussed by [[Francis Bacon]] in [[1620]] in his ''Novum Organum''. The first written scientific reflection on the microscopic nature of heat is probably to be found in a work by [[Mikhail Lomonosov]], in which he wrote:
:"(..) movement should not be denied based on the fact it is not seen. Who would deny that the leaves of trees move when rustled by a wind, despite it being unobservable from large distances? Just as in this case motion remains hidden due to perspective, it remains hidden in warm bodies due to the extremely small sizes of the moving particles. In both cases, the viewing angle is so small that neither the object nor their movement can be seen."
During the same years, [[Daniel Bernoulli]] published his book ''Hydrodynamics'' ([[1738]]), in which he derived an equation for the pressure of a gas considering the collisions of its atoms with the walls of a container. He proves that this pressure is two thirds the average kinetic energy of the gas in a unit volume. Bernoulli's ideas, however, made little impact on the dominant caloric culture. Bernoulli made a connection with [[Gottfried Leibniz]]'s ''[[vis viva]]'' principle, an early formulation of the principle of [[conservation of energy]], and the two theories became intimately entwined throughout their history. Though Benjamin Thompson suggested that heat was a form of motion as a result of his experiments in [[1798]], no attempt was made to reconcile theoretical and experimental approaches, and it is unlikely that he was thinking of the ''vis viva'' principle.
[[John Herapath]] later independently formulated a kinetic theory in [[1820]], but mistakenly associated temperature with [[momentum]] rather than ''vis viva'' or [[kinetic energy]]. His work ultimately failed [[peer review]] and was neglected. [[John James Waterston]] in [[1843]] provided a largely accurate account, again independently, but his work received the same reception, failing peer review even from someone as well-disposed to the kinetic principle as Davy.
Further progress in kinetic theory started only in the middle of the [[19th century]], with the works of [[Rudolf Clausius]], [[James Clerk Maxwell]], and [[Ludwig Boltzmann]]. In his [[1857]] work ''On the nature of the motion called heat'', Clausius for the first time clearly states that heat is the average kinetic energy of molecules. This interested Maxwell, who in [[1859]] derived the momentum distribution later named after him. Boltzmann subsequently generalized his distribution for the case of gases in external fields.
Boltzmann is perhaps the most significant contributor to kinetic theory, as he introduced many of the fundamental concepts in the theory. Besides the [[Boltzmann distribution]] mentioned above, he also associated the kinetic energy of particles with their [[degrees of freedom (physics and chemistry)|degrees of freedom]]. The [[Boltzmann equation]] for the distribution function of a gas in non-equilibrium states is still the most effective equation for studying transport phenomena in gases and metals. By introducing the concept of thermodynamic probability as the number of microstates corresponding to the current macrostate, he showed that its logarithm is proportional to entropy.
== Branches of ==
The following list gives a rough outline as to when the major branches of thermodynamics came into inception:
* [[Thermochemistry]] - 1780s
* [[Classical thermodynamics]] - 1824
* [[Phenomenological thermodynamics]]
* [[Chemical thermodynamics]] - 1876
* [[Statistical thermodynamics]] - c. 1880s
* [[Equilibrium thermodynamics]]
* [[Engineering thermodynamics]]
* [[Psychodynamics]] - c. 1920s
* [[Chemical engineering thermodynamics]] - c. 1940s
* [[Non-equilibrium thermodynamics]] - 1941
* [[Small systems thermodynamics]] - 1960s
* [[Biological thermodynamics]] - 1957
* [[Ecosystem thermodynamics]] - 1959
* [[Relativistic thermodynamics]] - 1965
* [[Quantum thermodynamics]] - 1968
* [[Molecular thermodynamics]] - 1969
* [[Thermoeconomics]] - c. 1970s
* [[Black hole thermodynamics]] - c. 1970s
* [[Geological thermodynamics]] - c. 1970s
* [[Biological evolution thermodynamics]] - 1978
* [[Geochemical thermodynamics]] - c. 1980s
* [[Atmospheric thermodynamics]] - c. 1980s
* [[Natural systems thermodynamics]] - 1990s
* [[Supramolecular thermodynamics]] - 1990s
* [[Earthquake thermodynamics]] - 2000
* [[Drug-receptor thermodynamics]] - 2001
* [[Pharmaceutical systems thermodynamics]] – 2002
== Entropy and the second law ==
{{main|History of entropy}}
Even though he was working with the caloric theory, [[Nicolas Léonard Sadi Carnot|Sadi Carnot]] in [[1824]] suggested that some of the caloric available for generating useful work is lost in any real process. In March [[1851]], while grappling to come to terms with the work of [[James Prescott Joule]], [[Lord Kelvin]] started to speculate that there was an inevitable loss of useful heat in all processes. The idea was framed even more dramatically by [[Hermann von Helmholtz]] in [[1854]], giving birth to the spectre of the [[heat death of the universe]].
In [[1854]], [[William John Macquorn Rankine]] started to make use in calculation of what he called his ''thermodynamic function''. This has subsequently been shown to be identical to the concept of [[entropy]] formulated by [[Rudolf Clausius]] in [[1865]]. Clausius used the concept to develop his classic statement of the [[second law of thermodynamics]] the same year.
== Heat transfer ==
{{main|Heat transfer}}
The phenomenon of [[heat conduction]] is immediately grasped in everyday life. In [[1701]], Sir [[Isaac Newton]] published his [[Heat transfer#Newton's law of cooling|law of cooling]]. However, in the [[17th century]], it came to be believed that all materials had an identical conductivity and that differences in sensation arose from their different [[heat capacity|heat capacities]].
Suggestions that this might not be the case came from the new science of [[electricity]] in which it was easily apparent that some materials were good electrical conductors while others were effective insulators. [[Jan Ingen-Housz]] in [[1785]]-[[1789|9]] made some of the earliest measurements, as did Benjamin Thompson during the same period.
The fact that warm air rises and the importance of the phenomenon to meteorology was first realised by [[Edmund Halley]] in [[1686]]. Sir [[John Leslie (physicist)|John Leslie]] observed that the cooling effect of a stream of air increased with its [[speed]], in [[1804]].
[[Carl Wilhelm Scheele]] distinguished heat transfer by [[thermal radiation]] (radiant heat) from that by convection and conduction in [[1777]]. In [[1791]], [[Pierre Prévost]] showed that all bodies radiate heat, no matter how hot or cold they are. In 1804, Leslie observed that a matt black surface radiates heat more effectively than a polished surface, suggesting the importance of [[black body radiation]]. Though it had become to be suspected even from Scheele's work, in [[1831]] [[Macedonio Melloni]] demonstrated that black body radiation could be [[reflection (physics)|reflected]], [[refraction|refracted]] and [[polarisation|polarised]] in the same way as [[light]].
[[James Clerk Maxwell]]'s [[1862]] insight that both light and radiant heat were forms of [[electromagnetic wave]] led to the start of the [[quantitative]] analysis of thermal radiation. In [[1879]], [[Jožef Stefan]] observed that the total [[radiant flux]] from a blackbody is proportional to the fourth power of its temperature and stated the [[Stefan-Boltzmann law]]. The law was derived theoretically by [[Ludwig Boltzmann]] in [[1884]].
== Cryogenics ==
In [[1702]] [[Guillaume Amontons]] introduced the concept of [[absolute zero]] based on observations of [[gas]]es. In [[1810]], Sir John Leslie froze water to ice artificially. The idea of absolute zero was generalised in [[1848]] by Lord Kelvin. In [[1906]], [[Walther Nernst]] stated the [[third law of thermodynamics]].
== See also ==
* [[Conservation of energy#Historical development|Conservation of energy: Historical development]]
* [[History of Chemistry]]
* [[History of Physics]]
* [[Timeline of thermodynamics, statistical mechanics, and random processes]]
* [[Thermodynamics]]
* [[Timeline of heat engine technology]]
==References==
<references />
== Further reading ==
* {{cite book | author=Cardwell, D.S.L. | title=From Watt to Clausius: The Rise of Thermodynamics in the Early Industrial Age | publisher=Heinemann | location=London | year=1971 | id=ISBN 0-435-54150-1}}
* {{cite book | author=Leff, H.S. & Rex, A.F. (eds) | title=Maxwell's Demon: Entropy, Information and Computing | publisher=Adam Hilger | location=Bristol | year=1990 | id=ISBN 0-7503-0057-4}}
== External links ==
*[http://thermohistory.com/ Concise History of Thermodynamics] - ThermoHistory.com
*[http://history.hyperjeff.net/statmech History of Statistical Mechanics and Thermodynamics] - Timeline (1575 to 1980) @ Hyperjeff.net
*[http://www.mhtl.uwaterloo.ca/courses/me354/history.html History of Thermodynamics] - University of Waterloo
*[http://www.wolframscience.com/reference/notes/1019b Thermodynamic History Notes] - WolframScience.com
*[http://www.nuc.berkeley.edu/courses/classes/E-115/Slides/A_Brief_History_of_Thermodynamics.pdf Brief History of Thermodynamics] - Berkeley [PDF]
*[http://thermodynamicstudy.net/history.html History of Thermodynamics] - ThermodynamicStudy.net
*[http://che.konyang.ac.kr/COURSE/thermo/history/therm_his.html Historical Background of Thermodynamics] - Carnegie-Mellon University
*[http://www.nt.ntnu.no/users/haugwarb/Presentations/History%20of%20Thermodynamics/ History of Thermodynamics] - In Pictures
*[http://www.physics.northwestern.edu/Phyx103/web/thermo-dateline.html Dateline of Thermodynamics] - Physics at Northwestern University
[[Category:History of thermodynamics| ]]
[[fa:تاریخچه ترمودینامیک]]
[[ko:열역학의 역사]]