Iron-sulfur cluster 97051 217912750 2008-06-08T08:00:54Z タチコマ robot 421426 robot Adding: [[pl:Centrum żelazowo-siarkowe]] For biological Fe-S clusters, see [[iron-sulfur protein]]s. '''Iron-sulfur clusters''' are ensembles of [[iron]] and [[sulfide]] centres. Fe-S clusters are most often discussed in the context of the biological role for [[iron-sulfur protein]]s.<ref>S. J. Lippard, J. M. Berg “Principles of Bioinorganic Chemistry” University Science Books: Mill Valley, CA; 1994. ISBN 0-935702-73-3.</ref> Many Fe-S clusters are known in the area of organometallic chemistry and as precursors to synthetic analogues of the biological clusters (see Figure). [[Image:FeS.png|thumb|center|600px|'''Figure.''' Illustrative synthetic Fe-S clusters. From left to right: Fe<sub>3</sub>S<sub>2</sub>(CO)<sub>9</sub>, [Fe<sub>3</sub>S(CO)<sub>9</sub>]<sup>2-</sup>, (C<sub>5</sub>H<sub>5</sub>)<sub>4</sub>Fe<sub>4</sub>S<sub>4</sub>, and [Fe<sub>4</sub>S<sub>4</sub>Cl<sub>4</sub>]<sup>2-</sup>.]] ==References== <references/> ==See also== * [[Bioinorganic chemistry]] ==External links== [[Category:Cluster chemistry]] [[Category:Iron compounds]] [[Category:Sulfur compounds]] [[it:Cluster ferro-zolfo]] [[pl:Centrum żelazowo-siarkowe]]