Terahertz time-domain spectroscopy 1240836 221000419 2008-06-22T16:24:40Z DOI bot 6652755 Citation maintenance. Initiated by [[User:Fconaway|Fconaway]]. You can [[WP:DOI|use this bot]] yourself! Please [[User:DOI_bot/bugs|report any bugs]]. {{Nofootnotes|date=February 2008}} [[Image:THz pulse.png|thumb|right|Typical pulse as measured with THz-TDS.]] [[Image:THz pulse spectrum.png|thumb|right|Fourier transform of the above pulse.]] In [[physics]], '''terahertz time-domain spectroscopy''' (THz-TDS) is a [[spectroscopy|spectroscopic]] technique where a special generation and detection scheme is used to probe material properties with short pulses of [[terahertz radiation]]. The generation and detection scheme is sensitive to the a sample material's effect on both the [[amplitude]] and the [[phase (waves)|phase]] of the terahertz radiation. In this respect, the technique can provide more information than conventional [[Fourier-transform spectroscopy]] that is only sensitive to the amplitude. The radiation has several distinct advantages over other forms of [[spectroscopy]]: many materials are transparent to THz, THz radiation is safe for biological [[Biological tissue|tissue]]s because it is [[non-ionizing radiation|non-ionizing]] (unlike for example [[X-rays]]), and images formed with terahertz radiation can have relatively good resolution (less than 1 mm). Also, many interesting materials have unique spectral fingerprints in the terahertz range, which means that terahertz radiation can be used to identify them. Examples which have been demonstrated include several different types of [[explosives]], polymorphic forms of many compounds used as Active Pharmaceutical Ingredients (API) in commercial medications as well as several illegal [[narcotic]] substances. Again, as many materials are quite transparent to THz radiation, these items of interest can be observed through normally opaque intervening layers (packaging, clothing). Additionally, though not strictly a spectroscopic technique, the ultrashort width of the THz radiation pulses allows for measurements (e.g., thickness, density, defect location) on difficult to probe materials (e.g., foam). The measurement capability shares many similarities to that observed with pulsed ultrasonic systems. Reflections off buried interfaces and defects can be found and precisely imaged. THz measurements are non-contact however. Typically, the terahertz pulses are generated by an [[ultrashort pulse]]d laser and last only a few picoseconds. A single pulse can contain frequency components covering the whole terahertz range from 0.05 to 4 THz. For detection, the electrical field of the terahertz pulse is [[sampling (signal processing)|sampled]] and digitized, conceptually similar to the way an audio card transforms electrical voltage levels in an audio signal into numbers that describe the audio waveform. In THz-TDS, the electrical field of the THz pulse interacts in the detector with a much-shorter laser pulse (e.g. 0.1 picoseconds) in a way that produces an electrical signal that is proportional to the electric field of the THz pulse at the time the laser pulse gates the detector on. By repeating this procedure and varying the timing of the gating laser pulse, it is possible to scan the THz pulse and construct its electric field as a function of time. Subsequently, a [[Fourier transform]] is used to extract the frequency spectrum from the time-domain data. ==Generation== There are two widely used techniques for generating terahertz pulses, both based on ultrashort pulses from [[Ti-sapphire laser|titanium-sapphire lasers]]. ===Photoconductive emitters=== In a photoconductive emitter, the optical laser pulse (100 femtoseconds or shorter) creates carriers (electron-hole pairs) in a [[semiconductor]] material. Effectively, the semiconductor changes abruptly from being an insulator into being a conductor. This conduction leads to a sudden electrical current across a biased antenna patterned on the semiconductor. This changing current emits terahertz radiation, similar to what happens in the antenna of a radio transmitter. Typically the two antenna [[electrode]]s are patterned on a low [[temperature]] [[gallium arsenide]] (LT-GaAs), semi-insulating [[gallium arsenide]] (SI-GaAs), or other semiconductor (such as InP) [[Wafer (electronics)|substrate]]. In a commonly used scheme, the electrodes are formed into the shape of a simple [[dipole antenna]] with a gap of a few micrometers and have a bias [[Potential difference|voltage]] up to 40 [[Volts|V]] between them. The ultrafast (100 [[femtosecond|fs]]) laser pulse, must have a wavelength that is short enough to excite electrons across the bandgap of the semiconductor substrate. This scheme is suitable for illumination with a [[Ti-sapphire oscillator|Ti:sapphire oscillator]] laser with pulse energies of about 10 nJ. For use with [[Chirped pulse amplification|amplified Ti:sapphire lasers]] with pulse energies of about 1 mJ, the electrode gap can be increased to several centimeters with a bias voltage of up to 10 kV. The short duration of THz pulses generated (typically ~2 [[picosecond|ps]]) are primarily due to the rapid rise of the photo-induced current in the semiconductor and the short carrier lifetime semiconductor materials (e.g., LT-GaAs). This current may persist for only a few hundred femtoseconds, up to several nanoseconds, depending on the material of which the substrate is composed. This is not the only means of generation, but is currently ([[as of 2008]]) the most common.{{Fact|date=July 2007}} Pulses produced by this method have average power levels on the order of [[nano]][[watt]]s, although the peak power during the pulses can be many orders of magnitude higher. The bandwidth of the resulting THz pulse is primarily limited by how quickly the charge carriers can accelerate in the semiconductor material, rather than the duration of the laser pulse. ===Optical rectification=== {{main|Optical rectification}} In [[optical rectification]], a high-intensity ultrashort laser pulse passes through a transparent crystal material that emits a terahertz pulse without any applied voltages. It is a [[nonlinear optics|nonlinear-optical]] process, where an appropriate crystal material is quickly [[polarization density|electrically polarized]] at high optical intensities. This changing electrical polarization emits terahertz radiation. Because of the high laser intensities that are necessary, this technique is mostly used with [[Chirped pulse amplification|amplified Ti:sapphire lasers]]. Typical crystal materials are [[zinc telluride]], [[gallium phosphide]], and gallium selenide. The bandwidth of pulses generated by optical rectification is limited by the laser pulse duration, terahertz absorption in the crystal material, the thickness of the crystal, and a mismatch between the propagation speed of the laser pulse and the terahertz pulse inside the crystal. Typically, a thicker crystal will generate higher intensities, but lower THz frequencies. With this technique, it is possible to boost the generated frequencies to 40 THz or higher, although 2 THz is more commonly used since it requires less complex optical setups. ==Detection== The electrical field of the terahertz pulses is measured in a detector that is simultaneously illuminated with an ultrashort laser pulse. Two common detection schemes are used in THz-TDS: photoconductive sampling and electro-optical sampling. THz pulses can also be detected by [[bolometer]]s, heat detectors cooled to liquid-helium temperatures. Since bolometers can only measure the total energy of a terahertz pulse, rather than its electrical field over time, it is not suitable for use in THz-TDS. In both detection methods, a part (called the ''detection pulse'') of the same ultrashort laser pulse that was used to generate the terahertz pulse is fed to the detector, where it arrives simultaneously with the terahertz pulse. The detector will produce a different electrical signal depending on whether the detection pulse arrives when the electric field of the THz pulse is low or high. An optical delay line is used to vary the timing of the detection pulse. Because the measurement technique is coherent, it naturally rejects [[incoherent]] radiation. Additionally, because the time slice of the measurement is extremely narrow, the noise contribution to the measurement is extremely low. The [[Signal-to-Noise]] (S/N) of the resulting time-domain waveform obviously depends on experimental conditions (e.g., averaging time), however due to the coherent sampling techniques described, high S/N values (>70 dB) are routinely seen with 1 minute averaging times. ===Photoconductive Detection=== Photoconductive detection is similar to photoconductive generation. Here, the bias electrical field across the antenna leads is generated by the electric field of the THz pulse focused onto the antenna, rather than being applied externally. The presence of the THz electric field generates current across the antenna leads, which is usually amplified using a low-bandwidth amplifier. This amplified current is the measured parameter which corresponds to the THz field strength. Again, the carriers in the semiconductor substrate have an extremely short lifetime. Thus, the THz electric field strength is only sampled for an extremely narrow slice (fs's) of the entire electric field waveform. ===Electro-optical sampling=== The materials used for generation by optical rectification can also be used for detection by using the [[Pockels effect]], where certain crystalline materials become birefringent in the presence of an electric field. The birefringence caused by the electric field of a terahertz pulse leads to a change in the optical [[polarization]] of the detection pulse, proportional to the electric-field strength. With the help of polarizers and [[photodiode]]s, this polarization change is measured. As with the generation, the bandwidth of the detection is dependent on the laser pulse duration, material properties, and crystal thickness. ==References and notes== {{Refimprove|date=December 2007}} {{reflist}} *{{cite journal | author = C. A. Schmuttenmaer | title = Exploring dynamics in the far-infrared with terahertz spectroscopy | journal = Chemical Reviews | volume = 104 | year = 2004 | url = http://www.chem.yale.edu/~cas/reprints/ChemRev_Reprint_withTitles.pdf | format = pdf | pages = 1759–1779 | doi = 10.1021/cr020685g }} ==See also== *[[optical rectification]] [[Category:Spectroscopy]] [[Category:Terahertz technology]] [[Category:Explosives detection]] [[ja:テラヘルツ時間領域分光]]